Preparation and structural characterisation of terpy-cored dendrimers and dendriplexes

被引：25

作者：

Constable, EC ^{[1
]}

Housecroft, CE ^{[1
]}

Neuburger, M ^{[1
]}

Schaffner, S ^{[1
]}

Scherer, LJ ^{[1
]}

机构：

[1] Univ Basel, Dept Chem, CH-4056 Basel, Switzerland

来源：

DALTON TRANSACTIONS | 2004年 / 17期

关键词：

D O I：

10.1039/b408605h

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

2,2':6',2"-Terpyridine (terpy) ligands and their iron(II) and cobalt(II) complexes bearing first and second generation Frechet-type dendritic wedges have been prepared and structurally characterised. The rotational freedom within the dendritic wedge results in a great diversity in conformational space. Structural studies are reported on first generation species and their metal complexes, and the variety of inter- and intramolecular interactions which dominate the conformation of the dendrimer and the packing of the molecules (ions) in the lattice are discussed.

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页码：2635 / 2642

页数：8

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