Local and average structure of lead titanate based ceramics

被引:17
作者
Frantti, J
Ivanov, S
Lappalainen, J
Eriksson, S
Lantto, V
Nishio, S
Kakihana, M
Rundlöf, H
机构
[1] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[2] Karpov Inst Phys Chem, Dept Inorgan Mat, Xray Lab, Moscow 103064 10, Russia
[3] Univ Oulu, Microelect & Mat Phys Lab, FIN-90014 Linnanmaa, Finland
[4] Uppsala Univ, Studsvik Neutron Res Lab, S-61182 Nykoping, Sweden
基金
芬兰科学院;
关键词
rare earth; lead zirconate titanate; local structure; neutron diffraction; Raman spectroscopy;
D O I
10.1080/00150190211446
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The revised lattice dynamics of Pb(ZrxTi1-x)O-3 (PZT) with 0.10 less than or equal to x less than or equal to 0.54 ceramics is reported. The phase transition from tetragonal phase to the monoclinic phase is proposed to occur via locally distorted regions. Neutron diffraction data suggests that these local regions transform to the monoclinic phase with decreasing temperature, when x approximate to 0.50.
引用
收藏
页码:73 / 90
页数:18
相关论文
共 30 条
[1]  
[Anonymous], MSH805 LANSCE LOS AL
[2]   Heterovalent and A-atom effects in A (B′B")O3 perovskite alloys [J].
Bellaiche, L ;
Padilla, J ;
Vanderbilt, D .
PHYSICAL REVIEW B, 1999, 59 (03) :1834-1839
[3]   Electrostatic model of atomic ordering in complex perovskite alloys [J].
Bellaiche, L ;
Vanderbilt, D .
PHYSICAL REVIEW LETTERS, 1998, 81 (06) :1318-1321
[4]   Finite-temperature properties of Pb(Zr1-xTix)O3 alloys from first principles [J].
Bellaiche, L ;
García, A ;
Vanderbilt, D .
PHYSICAL REVIEW LETTERS, 2000, 84 (23) :5427-5430
[5]   LATTICE MODES IN FERROELECTRIC PEROVSKITES - PBTIO3 [J].
BURNS, G ;
SCOTT, BA .
PHYSICAL REVIEW B, 1973, 7 (07) :3088-3101
[6]   Empirical cluster expansion models of cation order-disorder in A(B′1/3,B"2/3)O3 perovskites [J].
Burton, BP .
PHYSICAL REVIEW B, 1999, 59 (09) :6087-6091
[7]   A neutron diffraction investigation into the rhombohedral phases of the perovskite series PbZr1-xTixO3 [J].
Corker, DL ;
Glazer, AM ;
Whatmore, RW ;
Stallard, A ;
Fauth, F .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1998, 10 (28) :6251-6269
[8]   Normal to relaxor ferroelectric transformations in lanthanum-modified tetragonal-structured lead zirconate titanate ceramics [J].
Dai, XH ;
Xu, Z ;
Viehland, D .
JOURNAL OF APPLIED PHYSICS, 1996, 79 (02) :1021-1026
[9]   WEAK FERROELECTRICITY IN ANTIFERROELECTRIC LEAD ZIRCONATE [J].
DAI, XH ;
LI, JF ;
VIEHLAND, D .
PHYSICAL REVIEW B, 1995, 51 (05) :2651-2655
[10]   Ferroelectric and glassy states in La-modified lead zirconate titanate ceramics: A general picture [J].
El Marssi, M ;
Farhi, R ;
Dellis, JL ;
Glinchuk, MD ;
Seguin, L ;
Viehland, D .
JOURNAL OF APPLIED PHYSICS, 1998, 83 (10) :5371-5380