Local and average structure of lead titanate based ceramics

被引:17
作者
Frantti, J
Ivanov, S
Lappalainen, J
Eriksson, S
Lantto, V
Nishio, S
Kakihana, M
Rundlöf, H
机构
[1] Tokyo Inst Technol, Mat & Struct Lab, Midori Ku, Yokohama, Kanagawa 2268503, Japan
[2] Karpov Inst Phys Chem, Dept Inorgan Mat, Xray Lab, Moscow 103064 10, Russia
[3] Univ Oulu, Microelect & Mat Phys Lab, FIN-90014 Linnanmaa, Finland
[4] Uppsala Univ, Studsvik Neutron Res Lab, S-61182 Nykoping, Sweden
基金
芬兰科学院;
关键词
rare earth; lead zirconate titanate; local structure; neutron diffraction; Raman spectroscopy;
D O I
10.1080/00150190211446
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The revised lattice dynamics of Pb(ZrxTi1-x)O-3 (PZT) with 0.10 less than or equal to x less than or equal to 0.54 ceramics is reported. The phase transition from tetragonal phase to the monoclinic phase is proposed to occur via locally distorted regions. Neutron diffraction data suggests that these local regions transform to the monoclinic phase with decreasing temperature, when x approximate to 0.50.
引用
收藏
页码:73 / 90
页数:18
相关论文
共 30 条
[21]   Raman scattering on the B-site order controlled by A-site substitution in relaxor Perovskite ferroelectrics [J].
Jiang, FM ;
Kojima, S ;
Zhao, CL ;
Feng, CD .
JOURNAL OF APPLIED PHYSICS, 2000, 88 (06) :3608-3612
[22]   Anharmonicity and disorder in simple and complex perovskites:: a high energy synchrotron and hot neutron diffraction study [J].
Kiat, JM ;
Baldinozzi, G ;
Dunlop, M ;
Malibert, C ;
Dkhil, B ;
Ménoret, C ;
Masson, O ;
Fernandez-Diaz, MT .
JOURNAL OF PHYSICS-CONDENSED MATTER, 2000, 12 (39) :8411-8425
[23]   A monoclinic ferroelectric phase in the Pb(Zr1-xTix)O3 solid solution [J].
Noheda, B ;
Cox, DE ;
Shirane, G ;
Gonzalo, JA ;
Cross, LE ;
Park, SE .
APPLIED PHYSICS LETTERS, 1999, 74 (14) :2059-2061
[24]   Tetragonal-to-monoclinic phase transition in a ferroelectric perovskite:: The structure of PbZr0.52Ti0.48O3 [J].
Noheda, B ;
Gonzalo, JA ;
Cross, LE ;
Guo, R ;
Park, SE ;
Cox, DE ;
Shirane, G .
PHYSICAL REVIEW B, 2000, 61 (13) :8687-8695
[25]  
REANEY IM, 1996, P ELECTROCERAM, V1, P441
[26]   A TEM and neutron diffraction study of the local structure in the rhombohedral phase of lead zirconate titanate [J].
Ricote, J ;
Corker, DL ;
Whatmore, RW ;
Impey, SA ;
Glazer, AM ;
Dec, J ;
Roleder, K .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1998, 10 (08) :1767-1786
[27]   STRUCTURE OF THE DEFECT PEROVSKITE [PB0.85LA0.10]TIO3 BETWEEN 10 AND 1023 K [J].
ROSSETTI, GA ;
RODRIGUEZ, MA ;
NAVROTSKY, A ;
CROSS, LE ;
NEWNHAM, RE .
JOURNAL OF APPLIED PHYSICS, 1995, 77 (04) :1683-1689
[28]   X-RAY AND NEUTRON DIFFRACTION STUDY OF FERROELECTRIC PBTIO3 [J].
SHIRANE, G ;
PEPINSKY, R ;
FRAZER, BC .
ACTA CRYSTALLOGRAPHICA, 1956, 9 (02) :131-140
[29]   TRANSMISSION ELECTRON-MICROSCOPY STUDY OF HIGH-ZR-CONTENT LEAD-ZIRCONATE-TITANATE [J].
VIEHLAND, D .
PHYSICAL REVIEW B, 1995, 52 (02) :778-791
[30]   INCOMMENSURATION IN LA-MODIFIED ANTIFERROELECTRIC LEAD-ZIRCONATE-TITANATE CERAMICS [J].
XU, Z ;
DAI, XH ;
VIEHLAND, D .
APPLIED PHYSICS LETTERS, 1994, 65 (25) :3287-3289