Two 3D porous cadmium tetrazolate frameworks with hexagonal tunnels

被引：156

作者：

He, Xiang ^{[1
]}

Lu, Can-Zhong ^{[1
]}

Yuan, Da-Qiang ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

INORGANIC CHEMISTRY | 2006年 / 45卷 / 15期

关键词：

D O I：

10.1021/ic0520162

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two novel high-symmetry 3D porous frameworks, [Cd-5(tetrazolate)(9)(OH)(H2O)](n).5nH(2)O (1) and [Cd-5(5-aminotetrazolate) (9)-(NO3)](n).3nH(2)O ( 2), have been synthesized under hydrothermal conditions and characterized by single-crystal X-ray diffraction analysis. The structures of 1 and 2 are characteristic of hexagonal tunnels through the trigonal-prismatic and hexagonal tubelike building units and exhibit their high stabilities of porous frameworks against the removal of the guest molecules.

引用

页码：5760 / 5766

页数：7

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