Self-assembled discrete metal-organic complexes: Recent advances

被引:40
作者
Bilbeisi, Rana A. [1 ]
Olsen, John-Carl [2 ]
Charbonniere, Loic J. [3 ]
Trabolsi, Ali [1 ]
机构
[1] NYUAD, Ctr Sci & Engn, Abu Dhabi, U Arab Emirates
[2] Indiana Univ Kokomo, Sch Sci, Kokomo, IN 46904 USA
[3] UdS, CNRS, ECPM, IPHC,UMR 7178,Lab Ingn Mol Appl Anal, F-67200 Strasbourg, France
关键词
Chemical topology; Dynamic structural interconversions; Metal-organic complexes; Molecular capsules; Non-trivial structures; Template directed self-assembly; HOST-GUEST CHEMISTRY; COORDINATION CHEMISTRY; RATIONAL DESIGN; CAGE COMPLEXES; SPIN-CROSSOVER; SUPRAMOLECULAR CHEMISTRY; CRYSTALLINE CAPSULES; DIRECTED SYNTHESIS; BUILDING-BLOCKS; BINDING;
D O I
10.1016/j.ica.2013.12.015
中图分类号
O61 [无机化学];
学科分类号
070301 [无机化学];
摘要
Novelty, aesthetic appeal and the promise of a wide range of applications drive the current surge of interest in discrete metal-organic coordination complexes. This review covers achievements in the design, synthesis, characterization, and application of these multinuclear complexes in the years 2011-2013. Examples of their structural interconversion within dynamic combinatorial libraries are also presented. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码:79 / 108
页数:30
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