A new experimental protocol for intrazeolite photooxidations. The first product-based estimate of an upper limit for the intrazeolite singlet oxygen lifetime

被引：36

作者：

Pace, A

Clennan, EL ^{[1
]}

机构：

[1] Univ Wyoming, Dept Chem, Laramie, WY 82071 USA

[2] Univ Palermo, Dipartimento Chim Organ E Paterno, I-90128 Palermo, Italy

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2002年 / 124卷 / 38期

关键词：

D O I：

10.1021/ja027053w

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The intrazeolite photooxidations of several alkenes have been examined in hexane and in perfluorohexane slurries. The ability of perfluorohexane to increase the affinity of alkenes for the interior of the zeolite was documented. The nearly identical reaction rates in the two slurry solvents are attributed to a leveling of the singlet oxygen lifetime by the zeolite framework. A consideration of the rates of the various intrazeolite processes was used to estimate an upper limit for the intrazeolite lifetime of singlet oxygen. Copyright © 2002 American Chemical Society.

引用

页码：11236 / 11237

页数：2

共 24 条

[1] CATION-PI INTERACTIONS - NONADDITIVE EFFECTS ARE CRITICAL IN THEIR ACCURATE REPRESENTATION [J].