C(aryl)-O Activation of Aryl Carboxylates in Nickel-Catalyzed Biaryl Syntheses

被引：95

作者：

Goossen, Lukas J. ^{[1
]}

Goossen, Kaethe ^{[2
]}

Stanciu, Corneliu ^{[1
]}

机构：

[1] TU Kaiserslautern, FB Chem Organ Chem, D-67663 Kaiserslautern, Germany

[2] Bayer Schering Pharma AG, D-13353 Berlin, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 20期

关键词：

aryl carboxylates; biaryls; cross-coupling; homogeneous catalysis; nickel; CROSS-COUPLING REACTIONS; CARBON-CARBON BONDS; ARYLBORONIC ACIDS; SUZUKI-MIYAURA; ORGANOBORON COMPOUNDS; BORONIC ACIDS; ARENESULFONATES; REAGENTS; HALIDES; ETHERS;

D O I：

10.1002/anie.200900329

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Crucial breakthroughs in the activation of the C(aryl) - O bond of phenol derivatives were achieved almost simultaneously by two research groups (see scheme; Cy=cyclohexyl). Garg et al. coupled a range of aryl pivalates with arylboronic acids to give unsymmetrical biaryls. Shi et al. achieved this through C(aryl) - O activation of aryl carboxylates; the best results for the coupling of aryl boroxines were again obtained with aryl pivalates. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3569 / 3571

页数：3

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