A New Poly(thienylenevinylene) Derivative with High Mobility and Oxidative Stability for Organic Thin-Film Transistors and Solar Cells

被引:122
作者
Lim, Bogyu [1 ]
Baeg, Kang-Jun [1 ]
Jeong, Hyung-Gu [1 ]
Jo, Jang [1 ]
Kim, Hyungsoo [1 ]
Park, Jeong-Woo [1 ]
Noh, Yong-Young [2 ]
Vak, Doojin [1 ]
Park, Jeong-Ho [1 ]
Park, Ji-Woong [1 ]
Kim, Dong-Yu [1 ]
机构
[1] GIST, Dept Mat Sci & Engn, HCAM, Kwangju 500712, South Korea
[2] Elect & Telecommun Res Inst, Convergence Components & Mat Lab, Taejon 305350, South Korea
关键词
BAND-GAP; SEMICONDUCTORS; PERFORMANCE; POLYTHIOPHENE; THIOPHENE; POLYMERS; ELECTRON; COPOLYMERS; GATE; POLY(3-HEXYLTHIOPHENE);
D O I
10.1002/adma.200803700
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A novel thiophene-thienylenevinylene copolymer is synthesized and evaluated for use in organic field-effect transistors and organic solar cells. PETV12T shows good solution processability and high structural organization after annealing. Organic thin-film transistors based on the polymer exhibit high mobility and a high resistance to oxidation. In addition, PETV12T shows potential as an electron donor in bulk heterojunction solar cells.
引用
收藏
页码:2808 / +
页数:8
相关论文
共 52 条
[1]   Interaction of oxygen with conjugated polymers: Charge transfer complex formation with poly(3-alkylthiophenes) [J].
Abdou, MSA ;
Orfino, FP ;
Son, Y ;
Holdcroft, S .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (19) :4518-4524
[2]   Organic non-volatile memory based on pentacene field-effect transistors using a polymeric gate electret [J].
Baeg, Kang-Jun ;
Noh, Yong-Young ;
Ghim, Jieun ;
Kang, Seok-Ju ;
Lee, Hyemi ;
Kim, Dong-Yu .
ADVANCED MATERIALS, 2006, 18 (23) :3179-+
[3]   Soluble and processable regioregular poly(3-hexylthiophene) for thin film field-effect transistor applications with high mobility [J].
Bao, Z ;
Dodabalapur, A ;
Lovinger, AJ .
APPLIED PHYSICS LETTERS, 1996, 69 (26) :4108-4110
[4]   Photodegradation and photostabilization studies of poly(3-butylthiophene) in the solid state [J].
Caronna, T ;
Forte, M ;
Catellani, M ;
Meille, SV .
CHEMISTRY OF MATERIALS, 1997, 9 (04) :991-995
[5]   Enhanced mobility of poly(3-hexylthiophene) transistors by spin-coating from high-boiling-point solvents [J].
Chang, JF ;
Sun, BQ ;
Breiby, DW ;
Nielsen, MM ;
Sölling, TI ;
Giles, M ;
McCulloch, I ;
Sirringhaus, H .
CHEMISTRY OF MATERIALS, 2004, 16 (23) :4772-4776
[6]   Conjugated polymer photovoltaic cells [J].
Coakley, KM ;
McGehee, MD .
CHEMISTRY OF MATERIALS, 2004, 16 (23) :4533-4542
[7]   Molecular basis of mesophase ordering in a thiophene-based copolymer [J].
DeLongchamp, Dean M. ;
Kline, R. Joseph ;
Jung, Youngsuk ;
Lin, Eric K. ;
Fischer, Daniel A. ;
Gundlach, David J. ;
Cotts, Sarah K. ;
Moad, Andrew J. ;
Richter, Lee J. ;
Toney, Michael F. ;
Heeney, Martin ;
McCulloch, Iain .
MACROMOLECULES, 2008, 41 (15) :5709-5715
[8]   High carrier mobility polythiophene thin films: Structure determination by experiment and theory [J].
DeLongchamp, Dean M. ;
Kline, R. Joseph ;
Lin, Eric K. ;
Fischer, Daniel A. ;
Richter, Lee J. ;
Lucas, Leah A. ;
Heeney, Martin ;
McCulloch, Iain ;
Northrup, John E. .
ADVANCED MATERIALS, 2007, 19 (06) :833-+
[9]  
Dimitrakopoulos CD, 2002, ADV MATER, V14, P99, DOI 10.1002/1521-4095(20020116)14:2<99::AID-ADMA99>3.0.CO
[10]  
2-9