Micro-Raman spectroscopy for the crystallinity characterization of UHMWPE hip cups run on joint simulators

In this work Raman microspectrometry was used to evaluate the crystallinity changes of hip cups made of ultra-high molecular weight polyethylene (UHMWPE). In vitro experiments were carried out using hip joint movement-wear simulators, run for five million cycles in water or bovine calf serum. The hip cups were subjected to mechanical friction with ceramic femoral heads (alumina-zirconia blend). The crystallinity of the polymer hip cups was studied as a function of inner surface position and thickness, from the stressed surface to the unstressed outer one. The Partial Least Square (PLS-1) calibration was used to correlate the Raman spectra with the crystallinity of the polymer measured with DSC calorimetry. (C) 2000 Elsevier Science B.V. All rights reserved.