Preparation of cationic cobalt phenoxide and ethoxide complexes and their reversible reaction with carbon dioxide

被引：13

作者：

Archibald, SJ

Foxon, SP

Freeman, JD

Hobson, JE

Perutz, RN ^{[1
]}

Walton, PH

机构：

[1] Univ York, Dept Chem, York Y010 5DD, N Yorkshire, England

[2] Univ Hull, Dept Chem, Kingston Upon Hull HU6 7RX, N Humberside, England

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2002年 / 14期

关键词：

D O I：

10.1039/b204560e

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The complexes [Co(TCT)(OR)]BPh4 (R = Et, Ph; TCT = cis, cis-1,3,5- tris(cinnamylideneamino) cyclohexane) have been prepared and characterised by X-ray diffraction; in coordinating solvents both complexes react reversibly with carbon dioxide to form organocarbonate complexes.

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页码：2797 / 2799

页数：3

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