Synthesis and structure of polyhydroxyl rigid triangular nano-macrocyclic imine having multiple hydrogen-bonding sites

被引：49

作者：

Akine, S ^{[1
]}

Hashimoto, D ^{[1
]}

Saiki, T ^{[1
]}

Nabeshima, T ^{[1
]}

机构：

[1] Univ Tsukuba, Dept Chem, Tsukuba, Ibaraki 3058571, Japan

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 22期

关键词：

hydrogen bond; inclusion compound; macrocycle; molecular recognition; Schiff base;

D O I：

10.1016/j.tetlet.2004.04.015

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

42-Membered macrocyclic oligoimines based on the rigid biphenyl framework with 12 hydroxyl groups directing inward were synthesized by six-component cyclization without using a template. In the crystalline state, six dimethylsulfoxide molecules are bound simultaneously in a nano-sized cavity via hydrogen bonds. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：4225 / 4227

页数：3

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