Highly efficient addition of activated methylene compounds to alkenes catalyzed by gold and silver

被引：217

作者：

Yao, XQ ^{[1
]}

Li, CJ ^{[1
]}

机构：

[1] McGill Univ, Dept Chem, Montreal, PQ H3A 2K6, Canada

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2004年 / 126卷 / 22期

关键词：

D O I：

10.1021/ja0482637

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A highly efficient intermolecular addition of 1,3-diketones to alkenes catalyzed by AuCl3/AgOTf was developed. A mechanistic rationale for the reaction has been proposed via a α-C-H activation. Copyright © 2004 American Chemical Society.

引用

页码：6884 / 6885

页数：2

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