Incompletely condensed silsesquioxanes: Versatile tools in developing silica-supported olefin polymerization catalysts

被引：327

作者：

Duchateau, R ^{[1
]}

机构：

[1] Eindhoven Univ Technol, Dept Polymer Chem, NL-5600 MB Eindhoven, Netherlands

来源：

CHEMICAL REVIEWS | 2002年 / 102卷 / 10期

关键词：

D O I：

10.1021/cr010386b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Incompletely condensed silsesquioxanes were discussed. The support for heterogeneous olefin polymerization catalysts was amorphous silica gel. The results showed that silsesquioxanes resemble several features of silica surface silanol sites. It was found that the metallasilsesquioxane complexes were capable of mimicking characteristics of heterogeneous silica-supported transition-metal catalysts.

引用

页码：3525 / 3542

页数：18

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