Green, catalytic oxidations of alcohols

被引：1075

作者：

Sheldon, RA ^{[1
]}

Arends, IWCE ^{[1
]}

Ten Brink, GJ ^{[1
]}

Dijksman, A ^{[1
]}

机构：

[1] Delft Univ Technol Biocatalysis & Organ Chem, NL-2628 BL Delft, Netherlands

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2002年 / 35卷 / 09期

关键词：

D O I：

10.1021/ar010075n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three methods are described, in the context of the guiding principles of green chemistry, for the catalytic oxidation of alcohols. The first employs a recyclable oligomeric TEMPO catalyst (PIPO) and sodium hypochlorite as the oxidant in a bromide-free and chlorinated hydrocarbon solvent-free system. The second involves a ruthenium/TEMPO catalyst and oxygen as the oxidant. The third consists of a recyclable water-soluble palladium-diamine complex in conjunction with air as the oxidant in an aqueous biphasic system. The mechanisms of the ruthenium/TEMPO- and palladium-catalyzed oxidations are discussed, and the mechanism of the former is compared with that of the analogous copper/TEMPO catalyst.

引用

页码：774 / 781

页数：8

共 56 条

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