Green, catalytic oxidations of alcohols

被引：1075

作者：

Sheldon, RA ^{[1
]}

Arends, IWCE ^{[1
]}

Ten Brink, GJ ^{[1
]}

Dijksman, A ^{[1
]}

机构：

[1] Delft Univ Technol Biocatalysis & Organ Chem, NL-2628 BL Delft, Netherlands

来源：

ACCOUNTS OF CHEMICAL RESEARCH | 2002年 / 35卷 / 09期

关键词：

D O I：

10.1021/ar010075n

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Three methods are described, in the context of the guiding principles of green chemistry, for the catalytic oxidation of alcohols. The first employs a recyclable oligomeric TEMPO catalyst (PIPO) and sodium hypochlorite as the oxidant in a bromide-free and chlorinated hydrocarbon solvent-free system. The second involves a ruthenium/TEMPO catalyst and oxygen as the oxidant. The third consists of a recyclable water-soluble palladium-diamine complex in conjunction with air as the oxidant in an aqueous biphasic system. The mechanisms of the ruthenium/TEMPO- and palladium-catalyzed oxidations are discussed, and the mechanism of the former is compared with that of the analogous copper/TEMPO catalyst.

引用

页码：774 / 781

页数：8

共 56 条

[11] TEMPO oxidations with a silica-supported catalyst
Bolm, C
Fey, T
[J]. CHEMICAL COMMUNICATIONS, 1999, (18) : 1795 - 1796
[12] Production of hydrogen peroxide from oxygen and alcohols, catalyzed by palladium complexes
Bortolo, R
Bianchi, D
D'Aloisio, R
Querci, C
Ricci, M
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 153 (1-2) : 25 - 29
[13] Brunel D, 1999, STUD SURF SCI CATAL, V125, P237
[14] Cainelli G., 1984, CHROMIUM OXIDATIONS
[15] Efficient Mn-Cu and Mn-Co-TEMPO-catalysed oxidation of alcohols into aldehydes and ketones by oxygen under mild conditions
Cecchetto, A
Fontana, F
Minisci, F
Recupero, F
[J]. TETRAHEDRON LETTERS, 2001, 42 (38) : 6651 - 6653
[16] Chaudhuri P, 1998, ANGEW CHEM INT EDIT, V37, P2217, DOI 10.1002/(SICI)1521-3773(19980904)37:16<2217::AID-ANIE2217>3.0.CO
[17] 2-D
[18] Sol-gel entrapped TEMPO for the selective oxidation of methyl α-D-glucopyranoside
Ciriminna, R
Blum, J
Avnir, D
Pagliaro, M
[J]. CHEMICAL COMMUNICATIONS, 2000, (15) : 1441 - 1442
[19] deNooy AEJ, 1996, SYNTHESIS-STUTTGART, P1153
[20] Efficient ruthenium-TEMPO-catalysed aerobic oxidation of aliphatic alcohols into aldehydes and ketones
Dijksman, A
Arends, IWCE
Sheldon, RA
[J]. CHEMICAL COMMUNICATIONS, 1999, (16) : 1591 - 1592

← 1 2 3 4 5 6 →