3D Tailored Crumpling of Block-Copolymer Lithography on Chemically Modified Graphene

被引:59
作者
Kim, Ju Young [1 ]
Lim, Joonwon [1 ]
Jin, Hyeong Min [1 ]
Kim, Bong Hoon [1 ]
Jeong, Seong-Jun [1 ]
Choi, Dong Sung [1 ]
Li, Dong Jun [1 ]
Kim, Sang Ouk [1 ]
机构
[1] Korea Adv Inst Sci & Technol, Dept Mat Sci & Engn, Natl Creat Res Initiat Ctr Multidimens Directed N, Daejeon 34141, South Korea
基金
新加坡国家研究基金会;
关键词
3D; block copolymers; grapheme; instability; self-assembly; LARGE-AREA GRAPHENE; THIN-FILMS; SOLID-SURFACES; PATTERNS; ARRAYS; TEMPLATES; POLYMERS; LAYER; WATER; MULTIPLICATION;
D O I
10.1002/adma.201504590
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Novel 3D self-assembled nanopatterning is presented via tailored crumpling of chemically modified graphene. Block-copolymer self-assembly formed on a layer of chemically modified graphene provides highly dense and uniform 2D nanopatterns, and the controlled crumpling of the chemically modified graphene by mechanical instabilities realizes the controlled 3D transformation of the self-assembled nanopatterns.
引用
收藏
页码:1591 / 1596
页数:6
相关论文
共 54 条
  • [1] Spontaneous formation of ordered structures in thin films of metals supported on an elastomeric polymer
    Bowden, N
    Brittain, S
    Evans, AG
    Hutchinson, JW
    Whitesides, GM
    [J]. NATURE, 1998, 393 (6681) : 146 - 149
  • [2] Geometry and physics of wrinkling
    Cerda, E
    Mahadevan, L
    [J]. PHYSICAL REVIEW LETTERS, 2003, 90 (07) : 4
  • [3] Assembly of aligned linear metallic patterns on silicon
    Chai, Jinan
    Wang, Dong
    Fan, Xiangning
    Buriak, Jillian M.
    [J]. NATURE NANOTECHNOLOGY, 2007, 2 (08) : 500 - 506
  • [4] Buckling patterns of thin films on curved compliant substrates with applications to morphogenesis and three-dimensional micro-fabrication
    Chen, Xi
    Yin, Jie
    [J]. SOFT MATTER, 2010, 6 (22) : 5667 - 5680
  • [5] Simple and Versatile Methods To Integrate Directed Self-Assembly with Optical Lithography Using a Polarity-Switched Photoresist
    Cheng, Joy Y.
    Sanders, Daniel P.
    Truong, Hoa D.
    Harrer, Stefan
    Friz, Alexander
    Holmes, Steven
    Colburn, Matthew
    Hinsberg, William D.
    [J]. ACS NANO, 2010, 4 (08) : 4815 - 4823
  • [6] Templated self-assembly of block copolymers: Top-down helps bottom-up
    Cheng, Joy Y.
    Ross, Caroline A.
    Smith, Henry I.
    Thomas, Edwin L.
    [J]. ADVANCED MATERIALS, 2006, 18 (19) : 2505 - 2521
  • [7] Topography and instability of monolayers near domain boundaries
    Diamant, H
    Witten, TA
    Ege, C
    Gopal, A
    Lee, KYC
    [J]. PHYSICAL REVIEW E, 2001, 63 (06):
  • [8] The chemistry of graphene oxide
    Dreyer, Daniel R.
    Park, Sungjin
    Bielawski, Christopher W.
    Ruoff, Rodney S.
    [J]. CHEMICAL SOCIETY REVIEWS, 2010, 39 (01) : 228 - 240
  • [9] Nested self-similar wrinkling patterns in skins
    Efimenko, K
    Rackaitis, M
    Manias, E
    Vaziri, A
    Mahadevan, L
    Genzer, J
    [J]. NATURE MATERIALS, 2005, 4 (04) : 293 - 297
  • [10] Nanometer Scale Alignment of Block-Copolymer Domains by Means of a Scanning Probe Tip
    Felts, Jonathan R.
    Onses, M. Serdar
    Rogers, John A.
    King, William P.
    [J]. ADVANCED MATERIALS, 2014, 26 (19) : 2999 - 3002