Synthesis and applications of optically active metallacycles derived from primary amines

被引:33
作者
Albert, Joan [1 ]
Granell, Jaume [1 ]
Muller, Guillermo [1 ]
机构
[1] Univ Barcelona, Dept Quim Inorgan, E-08028 Barcelona, Spain
关键词
chiral; primary amine; palladacycles; phosphine; resolution;
D O I
10.1016/j.jorganchem.2005.10.041
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The synthesis of optically active cyclopalladated derivatives containing primary amines and their application as resolving agents of Lewis bases is reviewed. Some other applications such as the determination of the absolute configuration of coordinated chiral phosphines and the synthesis of chiral liquid crystals are also presented. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:2101 / 2106
页数:6
相关论文
共 68 条
  • [1] The cyclopalladation reaction of 2-phenylaniline revisited
    Albert, J
    Granell, J
    Zafrilla, J
    Font-Bardia, M
    Solans, X
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2005, 690 (02) : 422 - 429
  • [2] The cyclopalladation reaction of benzylamine revisited
    Albert, J
    Granell, J
    Tavera, R
    [J]. POLYHEDRON, 2003, 22 (02) : 287 - 291
  • [3] Albert J, 2002, CHEM-EUR J, V8, P2279, DOI 10.1002/1521-3765(20020517)8:10<2279::AID-CHEM2279>3.0.CO
  • [4] 2-#
  • [5] Cyclopalladation of the primary amine (R)-(+)-1-(1-naphthyl)ethylamine: A new resolving agent for monodentate phosphines
    Albert, J
    Cadena, JM
    Granell, J
    [J]. TETRAHEDRON-ASYMMETRY, 1997, 8 (07) : 991 - 994
  • [6] Albert J, 2000, EUR J INORG CHEM, P1283
  • [7] Synthesis and resolution of a new P-chiral hydroxy phosphine
    Albert, J
    Cadena, JM
    Delgado, S
    Granell, J
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 603 (02) : 235 - 239
  • [8] Cyclometallation of 2-phenylaniline and (R)-alpha-methylbenylamine by palladium(II) acetate. X-ray molecular structure of [Pd{2-(2'-NH2C6H4)C6H4}Br(PPh(3))]
    Albert, J
    Granell, J
    Luque, A
    Minguez, J
    Moragas, R
    FontBardia, M
    Solans, X
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 522 (01) : 87 - 95
  • [9] An approach to the synthesis of platinum complexes containing chiral monodentate phosphines with simultaneous regeneration of the resolving agent
    Albert, J
    Granell, J
    Minguez, J
    Muller, G
    Sainz, D
    Valerga, P
    [J]. ORGANOMETALLICS, 1997, 16 (15) : 3561 - 3564
  • [10] Resolution of benzylcyclohexylphenylphosphine by palladium(II)-amine metallacycles.: A new ligand for asymmetric hydrovinylation
    Albert, J
    Cadena, JM
    Granell, J
    Muller, G
    Ordinas, JI
    Panyella, D
    Puerta, C
    Sañudo, C
    Valerga, P
    [J]. ORGANOMETALLICS, 1999, 18 (17) : 3511 - 3518