Cyclopalladation of the primary amine (R)-(+)-1-(1-naphthyl)ethylamine: A new resolving agent for monodentate phosphines

被引:59
作者
Albert, J [1 ]
Cadena, JM [1 ]
Granell, J [1 ]
机构
[1] UNIV BARCELONA, DEPT QUIM INORGAN, E-08028 BARCELONA, SPAIN
关键词
D O I
10.1016/S0957-4166(97)00087-6
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
The cyclopalladation of the primary amine (R)-(+)-1-(1-naphthyl)ethylamine, available commercially, is described. The resolution of the monodentate phosphine trans-PPh2(2-HOC6H10) by means of the dinuclear cyclopalladated derivative is also reported (C) 1997 Elsevier Science Ltd.
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页码:991 / 994
页数:4
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