Tandem reactions on a zirconocene template

被引：44

作者：

Fillery, SF

Gordon, GJ

Luker, T

Whitby, RJ

机构：

[1] Department of Chemistry, Southampton University, Southampton, Hants

来源：

PURE AND APPLIED CHEMISTRY | 1997年 / 69卷 / 03期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1351/pac199769030633

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Co-cyclisation of alkenes with alkenes or alkynes and zirconocene gives zirconacycles which are further elaborated by the consecutive insertion of allyl, propargyl, or allenyl metal carbenoids and electrophiles. Insertion of other carbenoids give the first zirconacyclohexanes with the potential for further elaboration.

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页码：633 / 638

页数：6

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