Plasma-assisted atomic layer deposition of Al2O3 moisture permeation barriers on polymers

被引:218
作者
Langereis, E. [1 ]
Creatore, M. [1 ]
Heil, S. B. S. [1 ]
van de Sanden, M. C. M. [1 ]
Kessels, W. M. M. [1 ]
机构
[1] Eindhoven Univ Technol, Dept Appl Phys, NL-5600 MB Eindhoven, Netherlands
关键词
D O I
10.1063/1.2338776
中图分类号
O59 [应用物理学];
学科分类号
摘要
Thin Al2O3 films of different thicknesses (10-40 nm) were deposited by plasma-assisted atomic layer deposition on substrates of poly(2,6-ethylenenaphthalate) (PEN), and the water vapor transmission rate (WVTR) values were measured by means of the calcium test. The permeation barrier properties improved with decreasing substrate temperature and a good WVTR of 5x10(-3) g m(-2) day(-1) (WVTRPEN=0.5 g m(-2) day(-1)) was measured for a 20 nm thick Al2O3 film deposited at room temperature using short purging times. Such ultrathin, low-temperature deposited, high-quality moisture permeation barriers are an essential requirement for the implementation of polymeric substrates in flexible electronic and display applications.
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页数:3
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