Effect of filler dimensionality on the order-disorder transition of a model block copolymer nanocomposite

被引:36
作者
Jain, A
Gutmann, JS
Garcia, CBW
Zhang, YM
Tate, MW
Gruner, SM
Wiesner, U
机构
[1] Cornell Univ, Dept Mat Sci & Engn, Ithaca, NY 14853 USA
[2] Cornell Univ, Dept Phys, Ithaca, NY 14853 USA
关键词
D O I
10.1021/ma025511f
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
The effect of filler dimensionality on the order-disorder transition of a model block copolymer nanocomposite was discussed. It was found that the energetic influence of the filler particles arised from contact interactions between the individual polystyrene (PS) and polyisoprene (PI) blocks of the block copolymer matrix and the filler particle surface. The wettability of the filler particles imposed strong geometrical constraints on the block copolymer matrix.
引用
收藏
页码:4862 / 4865
页数:4
相关论文
共 26 条
[21]   Organically modified aluminosilicate mesostructures from block copolymer phases [J].
Templin, M ;
Franck, A ;
DuChesne, A ;
Leist, H ;
Zhang, YM ;
Ulrich, R ;
Schadler, V ;
Wiesner, U .
SCIENCE, 1997, 278 (5344) :1795-1798
[22]   Predicting the mesophases of copolymer-nanoparticle composites [J].
Thompson, RB ;
Ginzburg, VV ;
Matsen, MW ;
Balazs, AC .
SCIENCE, 2001, 292 (5526) :2469-2472
[23]  
Ulrich R, 1999, ADV MATER, V11, P141, DOI 10.1002/(SICI)1521-4095(199902)11:2<141::AID-ADMA141>3.0.CO
[24]  
2-R
[25]  
Yurekli K, 2001, J POLYM SCI POL PHYS, V39, P256, DOI 10.1002/1099-0488(20010115)39:2<256::AID-POLB80>3.0.CO
[26]  
2-Z