The effects of sulfation on the activity of Fe2O3 catalysts for methane oxidation

被引：8

作者：

Brown, ASC ^{[1
]}

Hargreaves, JSJ ^{[1
]}

Rijniersce, B ^{[1
]}

机构：

[1] Nottingham Trent Univ, Catalysis Res Lab, Nottingham NG11 8NS, England

来源：

TOPICS IN CATALYSIS | 2000年 / 11卷 / 1-4期

关键词：

superacidic; sulfated; iron oxide; goethite; ferrihydrite; haematite;

D O I：

10.1023/A:1027290201560

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

The effects of sulfation on iron oxides prepared from goethite and ferrihydrite for methane oxidation have been investigated. Reaction performance has been shown to be influenced by the iron oxide precursor. Sulfation produces a number of general effects, in addition to enhancing catalyst surface area, it suppresses the oxidation activity of Fe2O3 observed at 400 degrees C and below, whilst enhancing that at higher temperatures. Selective partial oxidation products - CH3OH and C2H6 - are also observed in some instances with sulfated systems.

引用

页码：181 / 184

页数：4

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