From a bismuth oxido diketonate to a giant bismuth oxido cluster

被引：43

作者：

Dikarev, Evgeny V. ^{[1
]}

Zhang, Haitao ^{[1
]}

Li, Bo ^{[1
]}

机构：

[1] Univ Albany, Dept Chem, Albany, NY 12222 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 33期

关键词：

bismuth; cluster compounds; O ligands; oxido ligands;

D O I：

10.1002/anie.200601675

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Aggregation in coordinating solvents: A giant oxido cluster [Bi 38O45(hfac)24] (hfac = hexafluoroacetylacetonate), formed in solutions of bismuth oxido diketonate [Bi9O7(hfac)13], has been isolated and fully characterized. The [Bi38O45]24+ core (see picture: orange Bi, red O; central Bi6O9 unit is highlighted) is capped by 24 hfac ligands, has a size larger than 2 nm, and may serve as a model for investigating the chemistry of bismuth oxide nanoparticles. (Figure Presented). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：5448 / 5451

页数：4

共 36 条

[1]

[Anonymous], ANGEW CHEM

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