Dynamical self-assembly of nanocrystal superlattices during colloidal droplet evaporation by in situ small angle x-ray scattering -: art. no. 135503

被引:199
作者
Narayanan, S [1 ]
Wang, J
Lin, XM
机构
[1] Argonne Natl Lab, Adv Photon Source, Argonne, IL 60439 USA
[2] Argonne Natl Lab, Div Mat Sci, Argonne, IL 60439 USA
[3] Argonne Natl Lab, Div Chem, Argonne, IL 60439 USA
[4] Argonne Natl Lab, Ctr Nanoscale Mat, Argonne, IL 60439 USA
关键词
D O I
10.1103/PhysRevLett.93.135503
中图分类号
O4 [物理学];
学科分类号
0702 ;
摘要
The nucleation and growth kinetics of highly ordered gold nanocrystal superlattices during the evaporation of nanocrystal colloidal droplets was elucidated by in situ time-resolved small-angle x-ray scattering. We demonstrated for the first time that the evaporation rate can affect the dimensionality of the superlattices. The formation of two-dimensional nanocrystal superlattices at the liquid-air interface of the droplet has exponential growth kinetics that originates from interface crushing.
引用
收藏
页码:135503 / 1
页数:4
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