Regio- and enantio-selective allylic alkylation catalysed by a chiral monophosphine-palladium complex

被引：118

作者：

Hayashi, T

Kawatsura, M

Uozumi, Y

机构：

[1] Department of Chemistry, Faculty of Science, Kyoto University, Sakyo

来源：

CHEMICAL COMMUNICATIONS | 1997年 / 06期

关键词：

D O I：

10.1039/a700045f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Allylic alkylation of racemic 1-arylprop-2-enyl acetates [ArCH(OAc)CH=CH2] with the sodium enolate of dimethyl methylmalonate in the presence of a palladium catalyst coordinated with (R)-2-diphenylphosphino-2'-methoxyl-1,1'-binaphthyl [(R)-MeO-MOP] proceeds with high branch selectivity (90%) to give chiral products [ArC*H-(Nu)CH=CH2] of up to 87% ee.

引用

页码：561 / 562

页数：2

共 17 条

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