Lanthanide-isophthalate cavity frameworks encapsulated copper(I) complexes

被引：12

作者：

Zhou, Youfu ^{[1
]}

Yuan, Daqiang ^{[1
]}

Jiang, Feilong ^{[1
]}

Xu, Yanqing ^{[1
]}

Hong, Maochun ^{[1
]}

机构：

[1] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fujian 350002, Peoples R China

来源：

JOURNAL OF MOLECULAR STRUCTURE | 2006年 / 796卷 / 1-3期

基金：

中国国家自然科学基金;

关键词：

lanthanide; copper; inclusion compounds; heterometallic complexes; properties; CADMIUM COORDINATION POLYMER; MAGNETIC-PROPERTIES; CRYSTAL-STRUCTURES; METAL COORDINATION; BRIDGING LIGAND; GD-III; CHEMISTRY; NETWORK; ND; FLUORESCENCE;

D O I：

10.1016/j.molstruc.2006.03.038

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The hydrothermal reactions of Ln(2)O(3), [Cu(2,2'-bpy)(2)](ClO4) and isophthalic acid (H(2)ip) yielded a series of heterometallic coordination frameworks with the empirical formula [{Ln(4)(ip)(7)(H2O)(2)}{Cu(bpy)(2)}(2)](n) [Ln=Nd (1), Sm (2), Eu (3)]. Single-crystal X-ray diffraction analyses reveal that they are isostructural and possess a 3D cavity framework with two complex cations [Cu(2,2-bpy)(2)](+) encapsulated in each cavity. TGA curve shows that they are highly thermally stable. Magnetic studies illustrate weakly antiferromagnetic exchange interactions between lanthanide(III) ions at room temperature in 1-3. Compound 2 has interesting photoluminescent property owing to the coexistence of host and guest photoluminescent units. (c) 2006 Published by Elsevier B.V.

引用

页码：203 / 209

页数：7

共 53 条

[1] Abrahams BF, 1998, ANGEW CHEM INT EDIT, V37, P2656, DOI 10.1002/(SICI)1521-3773(19981016)37:19<2656::AID-ANIE2656>3.0.CO
[2] 2-M
[3] STRUCTURE AND SPECTROSCOPIC AND MAGNETIC-PROPERTIES OF RARE-EARTH METAL(III) DERIVATIVES WITH THE 2-FORMYL-4-METHYL-6-(N-(2-PYRIDYLETHYL)FORMIMIDOYL)PHENOL LIGAND
ANDRUH, M
BAKALBASSIS, E
KAHN, O
TROMBE, JC
PORCHER, P
[J]. INORGANIC CHEMISTRY, 1993, 32 (09) : 1616 - 1622
[4] CRYSTAL-STRUCTURE OF LAFE(CN)6.5H2O
BAILEY, WE
WILLIAMS, RJ
MILLIGAN, WO
[J]. ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE, 1973, B 29 (JUL15): : 1365 - 1368
[5] Magnetism of lanthanides in molecular materials with transition-metal ions and organic radicals
Benelli, C
Gatteschi, D
[J]. CHEMICAL REVIEWS, 2002, 102 (06) : 2369 - 2387
[6] BIS(PENTAMETHYLCYCLOPENTADIENYL)YTTERBIUM(II) AS A LEWIS ACID AND ELECTRON-TRANSFER LIGAND - PREPARATION AND CRYSTAL-STRUCTURES OF [YB(ME5C5)2(MU-CO)XMN(CO)5-X]Y (X,Y=2 X=3,Y= INFINITY
BONCELLA, JM
ANDERSEN, RA
[J]. INORGANIC CHEMISTRY, 1984, 23 (04) : 432 - 437
[7] Lanthanide-containing molecular and supramolecular polymetallic functional assemblies
Bünzli, JCG
Piguet, C
[J]. CHEMICAL REVIEWS, 2002, 102 (06) : 1897 - 1928
[8] POLYNUCLEAR CU(12)(II)M(6)(III) (M=Y, ND, OR GD) COMPLEXES ENCAPSULATING A CLO4- ANION - [CU(12)M(6)(OH)(24)(H2O)(18)(PYB)(12)(CLO4)](CLO4)(17)CENTER-DOT-NH(2)O (PYB=PYRIDINE BETAINE)
CHEN, XM
AUBIN, SMJ
WU, YL
YANG, YS
MAK, TCW
HENDRICKSON, DN
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1995, 117 (37) : 9600 - 9601
[9] Polyoxometalate-based molecular materials
Coronado, E
Gomez-Garcia, CJ
[J]. CHEMICAL REVIEWS, 1998, 98 (01) : 273 - 296
[10] A general route to strictly dinuclear Cu(II)/Ln(III) complexes. Structural determination and magnetic behavior of two Cu(II)/Gd(III) complexes
Costes, JP
Dahan, F
Dupuis, A
Laurent, JP
[J]. INORGANIC CHEMISTRY, 1997, 36 (16) : 3429 - 3433

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