Synthesis and Magnetic Properties of Fe3O4 Nanoparticles Coated with Biocompatible Double Hydrophilic Block Copolymer

被引：14

作者：

Basina, G. ^{[2
]}

Mountrichas, G. ^{[1
]}

Devlin, E. ^{[2
]}

Boukos, N. ^{[2
]}

Niarchos, D. ^{[2
]}

Petridis, D. ^{[2
]}

Pispas, S. ^{[1
]}

Tzitzios, V. ^{[2
]}

机构：

[1] Natl Hellen Res Fdn, Inst Theoret & Phys Chem, GR-11635 Athens, Greece

[2] NCSR Demokritos Agia Paraskevi, Inst Mat Sci, Athens 15310, Greece

来源：

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2009年 / 9卷 / 08期

关键词：

Magnetite; Nanoparticles; Ferrofluids; Double Hydrophilic Block Copolymer; FTIR SPECTRAL CHARACTERIZATION; IRON-OXIDE NANOPARTICLES; THIN-FILM COATINGS; OLEIC-ACID; SIZE; FERROFLUIDS; DELIVERY; ALCOHOL; GLASSES; MEDIA;

D O I：

10.1166/jnn.2009.1275

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Fe3O4 nanoparticles coated with double hydrophilic biocompatible poly(sodium(2-sulfamate-3-carboxyl ate) isoprene)-b-poly (ethylene oxide) block copolymer were prepared by a one step precipitation method. The magnetic nanoparticles have 15 nm mean diameter (TEM), 68 nm hydrodynamic diameter, -30.10 mV zeta-potential and form very stable dispersion in aqueous media. Structural characterization using powder XRD and Mossbauer spectroscopy establish the magnetite phase, while thermogravimetric analysis and FT-IR spectroscopy confirm the presence of the block copolymer on the nanoparticles surface. The magnetic properties were determined using a vibrating sample magnetometer (VSM) at room temperature and reveal superparamagnetic behavior while the composite materials shows high saturation magnetization up to 67.7 emu/gr.

引用

页码：4753 / 4759

页数：7

共 37 条

[31] Sonochemical synthesis and characterization of pure nanometer-sized Fe3O4 particles [J].

Vijayakumar, R ;

Koltypin, Y ;

Felner, I ;

Gedanken, A .

MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2000, 286 (01) :101-105

[32] Size-controlled preparation of magnetite nanoparticles in the presence of graft copolymers [J].

Wan, SR ;

Huang, JS ;

Yan, HS ;

Liu, KL .

JOURNAL OF MATERIALS CHEMISTRY, 2006, 16 (03) :298-303

[33] Superparamagnetic latex via inverse emulsion polymerization [J].

Wormuth, K .

JOURNAL OF COLLOID AND INTERFACE SCIENCE, 2001, 241 (02) :366-377

[34] Synthesis and functionalization of polypyrrole-Fe3O4 nanoparticles for applications in biomedicine [J].

Wuang, Shy Chyi ;

Neoh, Koon Gee ;

Kang, En-Tang ;

Pack, Daniel W. ;

Leckband, Deborah E. .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (31) :3354-3362

[35] Development of high magnetization Fe3O4/polystyrene/silica nanospheres via combined miniemulsion/emulsion polymerization [J].

Xu, Hong ;

Cui, Longlan ;

Tong, Naihu ;

Gu, Hongchen .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (49) :15582-15583

[36] Highly ordered self-assembly with large area of Fe3O4 nanoparticles and the magnetic properties [J].

Yang, TZ ;

Shen, CM ;

Li, Z ;

Zhang, HR ;

Xiao, CW ;

Chen, ST ;

Xu, ZC ;

Shi, DX ;

Li, JQ ;

Gao, HJ .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (49) :23233-23236

[37] Magnetite (Fe3O4) core-shell nanowires:: Synthesis and magnetoresistance [J].

Zhang, DH ;

Liu, ZQ ;

Han, S ;

Li, C ;

Lei, B ;

Stewart, MP ;

Tour, JM ;

Zhou, CW .

NANO LETTERS, 2004, 4 (11) :2151-2155

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