Pd(0) supported onto monolithic polymers containing IL-like moieties. Continuous flow catalysis for the Heck reaction in near-critical EtOH

被引:83
作者
Karbass, Naima [1 ]
Sans, Victor [1 ]
Garcia-Verdugo, Eduardo [1 ]
Isabel Burguete, M. [1 ]
Luis, Santiago V. [1 ]
机构
[1] Univ Jaume 1, Dept Inorgan & Organ Chem, AU Adv Organ Mat, CSIC, E-12071 Castellon de La Plana, Spain
关键词
D O I
10.1039/b603224a
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Long-term stable Pd(0) catalysts can be easily supported onto polymeric monoliths containing methyl - imidazole moieties and the corresponding reactors based on these materials can be applied for the continuous Heck reaction in near-critical EtOH.
引用
收藏
页码:3095 / 3097
页数:3
相关论文
共 30 条
  • [1] Non-conventional methodologies for transition-metal catalysed carbon-carbon coupling: a critical overview. Part 1: The Heck reaction
    Alonso, F
    Beletskaya, IP
    Yus, M
    [J]. TETRAHEDRON, 2005, 61 (50) : 11771 - 11835
  • [2] Palladium N-methylimidazolium supported complexes as efficient catalysts for the Heck reaction
    Altava, B
    Burguete, MI
    García-Verdugo, E
    Karbass, N
    Luis, SV
    Puzary, A
    Sans, V
    [J]. TETRAHEDRON LETTERS, 2006, 47 (14) : 2311 - 2314
  • [3] The use of NIR-FT-Raman spectroscopy for the characterization of polymer-supported reagents and catalysts
    Altava, B
    Burguete, MI
    García-Verdugo, E
    Luis, SV
    Vicent, MJ
    [J]. TETRAHEDRON, 2001, 57 (41) : 8675 - 8683
  • [4] Altava B, 2000, ANGEW CHEM INT EDIT, V39, P1503, DOI 10.1002/(SICI)1521-3773(20000417)39:8<1503::AID-ANIE1503>3.0.CO
  • [5] 2-B
  • [6] Biffis A, 2001, EUR J INORG CHEM, P1131
  • [7] Palladium metal catalysts in Heck C-C coupling reactions
    Biffis, A
    Zecca, M
    Basato, M
    [J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2001, 173 (1-2) : 249 - 274
  • [8] Preparation of polymer-supported palladium/N-heterocyclic carbene complex for Suzuki cross-coupling reactions
    Byun, JW
    Lee, YS
    [J]. TETRAHEDRON LETTERS, 2004, 45 (09) : 1837 - 1840
  • [9] Functional resins in palladium catalysis: Promising materials for Heck reaction in aprotic polar solvents
    Caporusso, AM
    Innocenti, P
    Aronica, LA
    Vitulli, G
    Gallina, R
    Biffis, A
    Zecca, M
    Corain, B
    [J]. JOURNAL OF CATALYSIS, 2005, 234 (01) : 1 - 13
  • [10] Transition-metal nanoparticles in imidazolium ionic liquids: Recycable catalysts for biphasic hydrogenation reactions
    Dupont, J
    Fonseca, GS
    Umpierre, AP
    Fichtner, PFP
    Teixeira, SR
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (16) : 4228 - 4229