Fiber reinforced plastics using a new heat-resistant silicon based polymer

被引:52
作者
Itoh, M
Inoue, K
Hirayama, N
Sugimoto, M
Seguchi, T
机构
[1] Fukushima Natl Coll Technol, Iwaki, Fukushima 9708034, Japan
[2] Mitsubishi Chem Inc, Mat Sci Lab, Sodegaura, Chiba 2990265, Japan
[3] Nittobo FRP Lab Co Ltd, Koriyama, Fukushima 9638061, Japan
[4] Japan Atom Energy Res Inst, Takasaki Radiat Chem Res Estab, Takasaki, Gumma 3701233, Japan
关键词
Polymer; Silicon; Carbon Fiber; Glass Fiber; Polyimide;
D O I
10.1023/A:1016538014803
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Fiber reinforced plastics (FRPs), reinforced with carbon fiber, SiC fiber and glass fiber, were prepared by using a new thermosetting silicon-containing polymer, poly[(phenylsilylene) ethynylene-1,3-phenyleneethynylene](MSP), as a matrix resin. In MSP composite processing, no solvent is needed, no by-products are generated, and the curing temperature is low (150-210degreesC). The FRPs (MSP composite) showed high heat-, burn- and radiation-resistant properties. Bending strengths (110-140 MPa) and modulus (30 GPa) at 200degreesC and 400degreesC were almost equal with those at room temperature, and were not affected by 100 MGy of irradiation. Dynamic viscoelasticity and creep properties of MSP composite were also determined and compared with those of a polyimide composite. (C) 2002 Kluwer Academic Publishers.
引用
收藏
页码:3795 / 3801
页数:7
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