Green oxidation catalysis for rapid deactivation of bacterial spores

被引：48

作者：

Banerjee, Deboshri

Markley, Andrew L.

Yano, Toshihiro

Ghosh, Anindya

Berget, Peter B.

Minkley, Edwin G., Jr.

Khetan, Sushil K.

Collins, Terrence J.

机构：

[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA

[2] Mol Mat Sci Dept, Sumiyoshi Ku, Osaka 5588585, Japan

[3] Carnegie Mellon Univ, Dept Biol Sci, Pittsburgh, PA 15213 USA

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 24期

关键词：

green chemistry; homogeneous catalysis; iron; peroxides; spore deactivation;

D O I：

10.1002/anie.200504511

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) A view to a kill: Iron(III)-coordinated tetraamide macrocyclic ligands (see example) activate peroxides in water in the presence of a cationic surfactant to rapidly deactivate spores of the common anthrax surrogate, Bacillus atrophaeus. A 99.99999% kill can be achieved in 15 min at pH 10 and room temperature with tertbutyl hydroperoxide (see TEM images). © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3974 / 3977

页数：4

共 27 条

[1] BACTERICIDAL ACTIVITY OF ALKYL PEROXYL RADICALS GENERATED BY HEME-IRON-CATALYZED DECOMPOSITION OF ORGANIC PEROXIDES [J].