Hydrogen storage in metal-organic frameworks

被引：4103

作者：

Murray, Leslie J. ^{[1
]}

Dinca, Mircea ^{[1
]}

Long, Jeffrey R. ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2009年 / 38卷 / 05期

关键词：

GAS SORPTION PROPERTIES; PRUSSIAN BLUE ANALOGS; HIGH H-2 ADSORPTION; INELASTIC NEUTRON-SCATTERING; SECONDARY BUILDING UNITS; HIGH THERMAL-STABILITY; MOLECULAR-HYDROGEN; COORDINATION POLYMER; SINGLE-CRYSTAL; POROUS MATERIAL;

D O I：

10.1039/b802256a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

New materials capable of storing hydrogen at high gravimetric and volumetric densities are required if hydrogen is to be widely employed as a clean alternative to hydrocarbon fuels in cars and other mobile applications. With exceptionally high surface areas and chemically-tunable structures, microporous metal-organic frameworks have recently emerged as some of the most promising candidate materials. In this critical review we provide an overview of the current status of hydrogen storage within such compounds. Particular emphasis is given to the relationships between structural features and the enthalpy of hydrogen adsorption, spectroscopic methods for probing framework-H-2 interactions, and strategies for improving storage capacity

引用

页码：1294 / 1314

页数：21

共 187 条

[51] Design requirements for metal-organic frameworks as hydrogen storage materials [J].

Frost, Houston ;

Snurr, Randall Q. .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (50) :18794-18803

[52] Effects of surface area, free volume, and heat of adsorption on hydrogen uptake in metal-organic frameworks [J].

Frost, Houston ;

Dueren, Tina ;

Snurr, Randall Q. .

JOURNAL OF PHYSICAL CHEMISTRY B, 2006, 110 (19) :9565-9570

[53] Independent verification of the saturation hydrogen uptake in MOF-177 and establishment of a benchmark for hydrogen adsorption in metal-organic frameworks [J].

Furukawa, Hiroyasu ;

Miller, Michael A. ;

Yaghi, Omar M. .

JOURNAL OF MATERIALS CHEMISTRY, 2007, 17 (30) :3197-3204

[54] Enthalpy-entropy correlation for hydrogen adsorption on zeolites [J].

Garrone, E. ;

Bonelli, B. ;

Arean, C. Otero .

CHEMICAL PHYSICS LETTERS, 2008, 456 (1-3) :68-70

[55] The role of steps in the dynamics of hydrogen dissociation on Pt(533) [J].

Gee, AT ;

Hayden, BE ;

Mormiche, C ;

Nunney, TS .

JOURNAL OF CHEMICAL PHYSICS, 2000, 112 (17) :7660-7668

[56] FTIR investigation of the H2, N2, and C2H4 molecular complexes formed on the Cr(II) sites in the Phillips catalyst:: A preliminary step in the understanding of a complex system [J].

Groppo, E ;

Lamberti, C ;

Bordiga, S ;

Spoto, G ;

Damin, A ;

Zecchina, A .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (31) :15024-15031

[57] A lanthanide metal-organic framework with high thermal stability and available Lewis-acid metal sites [J].

Guo, Xiaodan ;

Zhu, Guangshan ;

Li, Zhongyue ;

Sun, Fuxing ;

Yang, Zhenghong ;

Qiu, Shilun .

CHEMICAL COMMUNICATIONS, 2006, (30) :3172-3174

[58] The inconsistency in adsorption properties and powder XRD data of MOF-5 is rationalized by framework interpenetration and the presence of organic and inorganic species in the nanocavities [J].

Hafizovic, Jasmina ;

Bjorgen, Morten ;

Olsbye, Unni ;

Dietzel, Pascal D. C. ;

Bordiga, Silvia ;

Prestipino, Carmelo ;

Lamberti, Carlo ;

Lillerud, Karl Petter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (12) :3612-3620

[59] Covalent organic frameworks as exceptional hydrogen storage materials [J].

Han, Sang Soo ;

Furukawa, Hiroyasu ;

Yaghi, Omar M. ;

Goddard, William A., III .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (35) :11580-+

[60] Metal-organic frameworks provide large negative thermal expansion Behavior [J].

Han, Sang Soo ;

Goddard, William A., III .

JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (42) :15185-15191

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