Well-defined carbon nanoparticles prepared from water-soluble shell cross-linked micelles that contain polyacrylonitrile cores

被引:106
作者
Tang, CB
Qi, K
Wooley, KL
Matyjaszewski, K
Kowalewski, T
机构
[1] Carnegie Mellon Univ, Dept Chem, Pittsburgh, PA 15213 USA
[2] Washington Univ, Dept Chem, St Louis, MO 63130 USA
关键词
block copolymers; carbon; nanostructures; pyrolysis;
D O I
10.1002/anie.200353401
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An alternative approach to nanostructured carbon materials relies on the use of covalently stabilized micellar precursors that are soluble in aqueous systems (see picture). These precursors belong to a class of shell cross-linked nanoparticles (SCKs) that are formed by self-assembly and stabilization of amphiphilic block copolymers.
引用
收藏
页码:2783 / 2787
页数:5
相关论文
共 46 条
[31]   AN INDUCTION FURNACE FOR OPERATIONS UP TO 3400 DEGREES C USING WELL ORIENTED GRAPHITE [J].
MOORE, AW ;
UBBELOHDE, AR ;
YOUNG, DA .
BRITISH JOURNAL OF APPLIED PHYSICS, 1962, 13 (08) :393-&
[32]   Thermal shaping of shell-crosslinked (SCK) nanoparticles, facilitated by nanoconfinement of fluid-like cores [J].
Murthy, KS ;
Ma, QG ;
Remsen, EE ;
Kowalewski, T ;
Wooley, KL .
JOURNAL OF MATERIALS CHEMISTRY, 2003, 13 (11) :2785-2795
[33]   1ST-ORDER AND 2ND-ORDER RAMAN-SCATTERING FROM FINITE-SIZE CRYSTALS OF GRAPHITE [J].
NEMANICH, RJ ;
SOLIN, SA .
PHYSICAL REVIEW B, 1979, 20 (02) :392-401
[34]   Polymers with very low polydispersities from atom transfer radical polymerization [J].
Patten, TE ;
Xia, JH ;
Abernathy, T ;
Matyjaszewski, K .
SCIENCE, 1996, 272 (5263) :866-868
[35]   Copper(I)-catalyzed atom transfer radical polymerization [J].
Patten, TE ;
Matyjaszewski, K .
ACCOUNTS OF CHEMICAL RESEARCH, 1999, 32 (10) :895-903
[36]   APPLICATION OF CARBON NANOTUBES AS SUPPORTS IN HETEROGENEOUS CATALYSIS [J].
PLANEIX, JM ;
COUSTEL, N ;
COQ, B ;
BROTONS, V ;
KUMBHAR, PS ;
DUTARTRE, R ;
GENESTE, P ;
BERNIER, P ;
AJAYAN, PM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (17) :7935-7936
[37]   Load transfer in carbon nanotube epoxy composites [J].
Schadler, LS ;
Giannaris, SC ;
Ajayan, PM .
APPLIED PHYSICS LETTERS, 1998, 73 (26) :3842-3844
[38]   Multiple pH-induced morphological changes in aggregates of polystyrene-block-poly(4-vinylpyridine) in DMF/H2O mixtures [J].
Shen, HW ;
Zhang, LF ;
Eisenberg, A .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (12) :2728-2740
[39]   Preparation of polyacrylonitrile-block-poly(n-butyl acrylate) copolymers using atom transfer radical polymerization and nitroxide mediated polymerization processes [J].
Tang, CB ;
Kowalewski, T ;
Matyjaszewski, K .
MACROMOLECULES, 2003, 36 (05) :1465-1473
[40]   Organically modified aluminosilicate mesostructures from block copolymer phases [J].
Templin, M ;
Franck, A ;
DuChesne, A ;
Leist, H ;
Zhang, YM ;
Ulrich, R ;
Schadler, V ;
Wiesner, U .
SCIENCE, 1997, 278 (5344) :1795-1798