Enhanced performance of sulfone-based electrolytes at lithium ion battery electrodes, including the LiNi0.5Mn1.5O4 high voltage cathode

被引：78

作者：

Xue, Leigang ^{[1
]}

Ueno, Kazuhide ^{[1
]}

Lee, Seung-Yul ^{[1
]}

Angell, C. Austen ^{[1
]}

机构：

[1] Arizona State Univ, Dept Chem & Biochem, Tempe, AZ 85287 USA

来源：

JOURNAL OF POWER SOURCES | 2014年 / 262卷

关键词：

Lithium ion battery; Sulfone-based electrolytes; High voltage electrolyte; 99-100% coulombic efficiency at LNMO cathode; High capacity retention; LIQUIDS; LIBOB;

D O I：

10.1016/j.jpowsour.2014.03.099

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

In an extension of our previous studies of sulfone-containing electrolytes for lithium batteries, we report tests of sulfone-carbonate, and all-sulfone, electrolytes in a variety of anode and cathode half cells. While the all-sulfone electrolyte appears promising at the graphite anode in early cycles, it fails at the high voltage cathode and will not be further tested. On the other hand a sulfone-carbonate mixed solvent performs very well (97% capacity retention after 100 cycles with 99-100% coulomb efficiency) at the LiNi0.5M1.5O4 (LNMO) cathode, and also at the Li4Ti5O12 (LTO) anode, both of which are being developed for high power applications. Published by Elsevier B.V.

引用

页码：123 / 128

页数：6

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