Further remarks on the heat capacity of the restricted primitive model

被引:11
作者
Valleau, J [1 ]
Torrie, G
机构
[1] Univ Toronto, Dept Chem, Chem Phys Theory Grp, Toronto, ON M5S 3H6, Canada
[2] Royal Mil Coll Canada, Dept Chem, Kingston, ON K7K 7B4, Canada
关键词
D O I
10.1063/1.1494431
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This concerns the critical behavior of the restricted primitive model. Luijten, Fisher, and Panagiotopoulos [J. Chem. Phys. 114, 5468 (2001)] recently suggested that canonical heat capacity data previously published by us might be consistent with nonclassical behavior, which had appeared unlikely to us. Their argument turns on a supposed similarity of behavior of our results with results they have obtained for a lattice version of the model. We point out that the behaviors are in fact very dissimilar, however, and we explain why we do not find their suggestion plausible. (C) 2002 American Institute of Physics.
引用
收藏
页码:3305 / 3309
页数:5
相关论文
共 10 条
[1]  
Fisher ME, 1996, J PHYS-CONDENS MAT, V8, P9103, DOI 10.1088/0953-8984/8/47/002
[2]   The heat capacity of the restricted primitive model electrolyte [J].
Luijten, E ;
Fisher, ME ;
Panagiotopoulos, AZ .
JOURNAL OF CHEMICAL PHYSICS, 2001, 114 (13) :5468-5471
[3]   Critical parameters of the restricted primitive model [J].
Panagiotopoulos, AZ .
JOURNAL OF CHEMICAL PHYSICS, 2002, 116 (07) :3007-3011
[4]   Coexistence and criticality in size-asymmetric hard-core electrolytes [J].
Romero-Enrique, JM ;
Orkoulas, G ;
Panagiotopoulos, AZ ;
Fisher, ME .
PHYSICAL REVIEW LETTERS, 2000, 85 (21) :4558-4561
[5]  
Stell G, 1999, NATO ADV SCI I C-MAT, V529, P71
[6]   Phase separation in ionic fluids [J].
Stell, G .
JOURNAL OF PHYSICS-CONDENSED MATTER, 1996, 8 (47) :9329-9333
[7]   CRITICALITY AND PHASE-TRANSITIONS IN IONIC FLUIDS [J].
STELL, G .
JOURNAL OF STATISTICAL PHYSICS, 1995, 78 (1-2) :197-238
[8]   Heat capacity of the restricted primitive model near criticality [J].
Valleau, J ;
Torrie, G .
JOURNAL OF CHEMICAL PHYSICS, 1998, 108 (13) :5169-5172
[9]  
VALLEAU JP, UNPUB
[10]   CRITICALITY OF IONIC FLUIDS [J].
Weingaertner, Hermann ;
Schroeer, Wolffram .
ADVANCES IN CHEMICAL PHYSICS <D>, 2001, 116 :1-66