Baylis-Hillman reaction in [bdmim][[PF6] ionic liquid

被引：98

作者：

Hsu, JC ^{[1
]}

Yen, YH ^{[1
]}

Chu, YH ^{[1
]}

机构：

[1] Natl Chung Cheng Univ, Dept Chem & Biochem, Chiayi 621, Taiwan

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 24期

关键词：

Baylis-Hillman reaction; ionic liquid;

D O I：

10.1016/j.tetlet.2004.04.099

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A new use of ionic liquid [bdmim][PF6] as solvent for the Baylis-Hillman reaction is presented. Unlike the commonly used [bmim][PF6] that evidently reacts with electrophilic aldehydes under basic conditions, ionic liquid [bdmim][PF6] is inert and the Baylis-Hillman reaction in [bdmim][PF6] proceeds smoothly with better yield. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：4673 / 4676

页数：4

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