Superior amine catalysts for the Baylis-Hillman reaction: the use of DBU and its implications

被引：252

作者：

Aggarwal, VK ^{[1
]}

Mereu, A ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 22期

关键词：

D O I：

10.1039/a907754e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

DBU, which is normally regarded as a hindered and non-nucleophilic base, is in fact the optimum catalyst for the Baylis-Hillman reaction, providing adducts at much faster rates than using DABCO or 3HQD; the scope of the Baylis-Hillman reaction is enhanced using this catalyst and implications of this finding are discussed.

引用

页码：2311 / 2312

页数：2

共 15 条

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