THE BAYLIS-HILLMAN REACTION-MECHANISM AND APPLICATIONS REVISITED

被引：106

作者：

FORT, Y ^{[1
]}

BERTHE, MC ^{[1
]}

CAUBERE, P ^{[1
]}

机构：

[1] UNIV NANCY 1,FAC SCI,CHIM ORGAN LAB 1,CNRS,URA 457,BP 239,F-54506 VANDOEUVRE NANCY,FRANCE

来源：

TETRAHEDRON | 1992年 / 48卷 / 31期

关键词：

D O I：

10.1016/S0040-4020(01)88227-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

It is shown that reaction of aryl, benzyl, alkyl and functionalised alkyl acrylic esters with benzaldehyde, in the presence of 1,4-diazabicyclo[2.2.2] octane, strongly depends upon the electronic and steric effects of the ester part. This influence is also observed in condensation of furfuraldehyde. Moreover, for the first time, it is shown that the overall condensation is equilibrated.

引用

页码：6371 / 6384

页数：14

共 21 条

[1]

[Anonymous], [No title captured], Patent No. [2155113A1, 2155113]

[2] A SIMPLE SYNTHESIS OF ALPHA-METHYLENE-BETA-HYDROXYALKANONES [J].