Stabilised phosphazides

被引：43

作者：

Bebbington, Magnus W. P. ^{[1
]}

Bourissou, Didier ^{[1
]}

机构：

[1] Univ Toulouse 3, Lab Heterochim Fondamentale & Appl, CNRS, UMR 5069,Equipe Ligands Bifonct & Polymers Biodeg, F-31062 Toulouse 9, France

来源：

COORDINATION CHEMISTRY REVIEWS | 2009年 / 253卷 / 9-10期

关键词：

Phosphazide; Staudinger; aza-Wittig reaction; Phosphazene; Azide; NITROARYL SUBSTITUTED PHOSPHAZIDES; STAUDINGER REACTION; MACROBICYCLIC TRIPHOSPHAZIDES; TERTIARY PHOSPHINES; AMBIPHILIC LIGANDS; AZIDES; COMPLEXES; TEMPERATURE; DERIVATIVES; REACTIVITY;

D O I：

10.1016/j.ccr.2008.08.009

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The Staudinger reaction between phosphines and azides provides a straightforward route to azaylides. Until the 1980s, it was thought that the putative intermediates of this reaction, namely phosphazides, were merely transient species that could be detected only by spectroscopic methods. This review summarises the achievements reported over the last 25 years on the preparation, structure and properties of phosphazides stabilised by substitution effects and/or coordination to transition metals or main group elements. Relevant computational studies on the Staudinger reaction are included. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：1248 / 1261

页数：14

共 75 条

[1] Ab initio SCF-MO study of the Staudinger phosphorylation reaction between a phosphane and an azide to form a phosphazene [J].