F-block N-heterocyclic carbene complexes

被引：155

作者：

Arnold, Polly L. ^{[1
]}

Liddle, Stephen T. ^{[1
]}

机构：

[1] Univ Nottingham, Sch Chem, Nottingham NG7 2RD, England

来源：

CHEMICAL COMMUNICATIONS | 2006年 / 38期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1039/b606829d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

N-Heterocyclic carbenes (NHCs) can bind as two-electron sigma-donor ligands to lanthanide and actinide metal cations. In this review we summarise how the incorporation of an anionic group (alkoxide or amido), to form heterobidentate NHC ligands, allows the synthesis of a range of f-block NHC adducts. The tethering group also allows the lability of the NHC group, and its subsequent reactivity, to be studied. We include a brief survey of the known, structurally characterised f-element-NHC bond distances, and a range of substrates that react to displace the metal-bound NHC group.

引用

页码：3959 / 3971

页数：13

共 85 条

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