Amino alcohols with the bicyclo[3.3.0]octane scaffold as ligands for the catalytic enantioselective addition of diethylzinc to aldehydes

被引：23

作者：

Zhong, YW ^{[1
]}

Lei, XS ^{[1
]}

Lin, GQ ^{[1
]}

机构：

[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Shanghai 200032, Peoples R China

来源：

TETRAHEDRON-ASYMMETRY | 2002年 / 13卷 / 20期

基金：

中国国家自然科学基金;

关键词：

D O I：

10.1016/S0957-4166(02)00584-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Amino alcohols with the bicyclo[3.3.0]octane framework were synthesized, characterized and used as chiral ligands for the addition of diethylzinc to aldehydes. Quantitative yields and enantiomeric excesses of up to 92% were obtained in the ethylation reactions. (C) 2002 Elsevier Science Ltd. All rights reserved.

引用

页码：2251 / 2255

页数：5