Dispersion polymerization of 1-vinyl-2-pyrrolidone in supercritical carbon dioxide

被引：57

作者：

Carson, T

Lizotte, J

Desimone, JM

机构：

[1] Univ N Carolina, Dept Chem, Venable & Kenan Labs, Chapel Hill, NC 27599 USA

[2] N Carolina State Univ, Dept Chem Engn, Raleigh, NC 27695 USA

来源：

MACROMOLECULES | 2000年 / 33卷 / 06期

关键词：

D O I：

10.1021/ma991222o

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

The low molecular weight poly (1,1-dihydroperfluorooctyl acrylate) [poly(FOA)] was used in the dispersion polymerization of 1-vinyl-2-pyrrolidone (VP) in supercritical CO2 Increasing concentrations of poly-(FOA) yielded a decrease in particle diameter, while increasing the monomer concentration produced an increase in particle size. No significant change was observed in the particle morphology for polymerizations conducted at different pressures.

引用

页码：1917 / 1920

页数：4

共 19 条

[11] DISPERSION POLYMERIZATION OF METHYL-METHACRYLATE STABILIZED WITH POLY(1,1-DIHYDROPERFLUOROOCTYL ACRYLATE) IN SUPERCRITICAL CARBON-DIOXIDE [J].