Effective cation-assisted chirality induction using a dibenzo-diaza-30-crown-10 with bis(zinc(II) porphyrin) units

被引：31

作者：

Kubo, Y ^{[1
]}

Ishii, Y ^{[1
]}

Yoshizawa, T ^{[1
]}

Tokita, S ^{[1
]}

机构：

[1] Saitama Univ, Fac Engn, Dept Appl Chem, Urawa, Saitama 3388570, Japan

来源：

CHEMICAL COMMUNICATIONS | 2004年 / 12期

关键词：

D O I：

10.1039/b403684k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first rationalized crown ether-bis(porphyrin) conjugate with a large ring-based conformation flexiblity 1 has been synthesized; the achiral-to-chiral transformation upon complexation with chiral diamines is assisted by K+ accommodated in the crowned moiety, and it is possible to determine the chirality of carboxylates as potassium salts.

引用

页码：1394 / 1395

页数：2

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