Synthesis and crystal structure of a novel tetraiminediphenolate iron(II) macrocyclic complex: A six-coordinate iron-protein model

被引：14

作者：

Raimondi, AC

Hitchcock, PB

Leigh, GJ

Nunes, FS

机构：

[1] Univ Fed Parana, Ctr Politecn, Dept Quim, BR-81531990 Curitiba, Parana, Brazil

[2] Univ Sussex, Sch Chem Phys & Environm Sci, Brighton BN1 9QJ, E Sussex, England

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2002年 / 32卷 / 10期

关键词：

iron(II); hexadentate-tetraiminediphenolate macrocyclic complex; crystal structure; FTIR spectroscopy; mass spectrometry;

D O I：

10.1023/A:1020261319440

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

A novel tetraiminediphenolate iron(II) macrocyclic complex [Fe(tidf)(CH3OH)(2)](NO3)(2) (1) has been prepared and characterized by microanalysis, X-ray crystallography, FTIR spectroscopy, and mass spectrometry. The crystal structure (monoclinic, space group C2/c, Z=8, a = 26.8573(6) Angstrom, b = 10.6551(4) Angstrom, c = 23.5371(7) Angstrom, beta = 107.450(2)degrees) shows that the iron(II) occupies a distorted octahedral geometry with two methanol molecules bound axially. The macrocyclic ligand is very flexible and adopts a butterfly conformation with a dihedral angle of 112degrees.

引用

页码：363 / 367

页数：5