Extremely efficient catalysis of immobilized lipase in ring-opening polymerization of lactones

被引:86
作者
Uyama, H
Suda, S
Kikuchi, H
Kobayashi, S
机构
[1] KYOTO UNIV, GRAD SCH ENGN, DEPT CHEM MAT, KYOTO 60601, JAPAN
[2] TOHOKU UNIV, GRAD SCH ENGN, DEPT CHEM MAT, SENDAI, MIYAGI 98077, JAPAN
关键词
D O I
10.1246/cl.1997.1109
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
An immobilized lipase derived from Candida antarctica was used as catalyst for the ring-opening polymerization of lactones. A small amount of the immobilized enzyme showed the extremely efficient catalysis in the lactone polymerization. The polymerization in the presence of 1-octanol enhanced the rate of reaction.
引用
收藏
页码:1109 / 1110
页数:2
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