Ni(0) catalysed homo-coupling reactions: a novel route towards the synthesis of multinuclear ruthenium polypyridine complexes featuring made-to-order properties

被引：30

作者：

Fanni, S

Di Pietro, C

Serroni, S ^{[1
]}

Campagna, S

Vos, JG

机构：

[1] Dublin City Univ, Sch Chem Sci, Inorgan Chem Res Ctr, Dublin 9, Ireland

[2] Univ Messina, Dipartimento Chim Inorgan Chim Analit & Chim Fis, I-98166 Messina, Italy

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 01期

关键词：

ruthenium complexes; coupling reactions; electrochemistry; dinuclear complexes;

D O I：

10.1016/S1387-7003(99)00182-3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new synthetic procedure for the efficient preparation of dinuclear ruthenium(II) polypyridyl complexes is reported. The compounds synthesised rue [(bpy)(2)Ru(BPBT)Ru(bpy)(2)] (PF6)(2) and [(bpy)(2)Ru(BPZBT)Ru(bpy)(2)](PF6)(2) (bpy = 2,2'-bipyridine; H2BPBT = 5,5'-bis(pyridin-2-yl)-3,3'-bis(1,2,4-triazole); H(2)BPZBT = 5,5'-bis(pyrazin-2-yl)-3,3'-bis( 1,2,4-triazole), Electrochemical experiments show that the two dinuclear systems investigated exhibit pH switchable intercomponent interactions. (C) 2000 Published by Elsevier Science S.A. All rights reserved.

引用

页码：42 / 44

页数：3

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