Coordination compounds as building blocks:: Single-step synthesis of heteronuclear multimetallic complexes containing RuII and OsII

被引：100

作者：

Connors, PJ ^{[1
]}

Tzalis, D ^{[1
]}

Dunnick, AL ^{[1
]}

Tor, Y ^{[1
]}

机构：

[1] Univ Calif San Diego, Dept Chem & Biochem, La Jolla, CA 92093 USA

来源：

INORGANIC CHEMISTRY | 1998年 / 37卷 / 05期

关键词：

D O I：

10.1021/ic970911i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel and powerful approach for the synthesis of heteromettalic complexes containing Ru-II and Os-II is described. Palladium-catalyzed cross-coupling reactions between [(bpy)(2)M-1(L1)](2+) and [(bpy)(2)M-2(L2)](2+) (where L1 and L2 are bromo- and ethynyl-functionalized 1,10-phenanthroline ligands) provide heteronuclear complexes in a single synthetic step.

引用

页码：1121 / 1123

页数：3

共 17 条

[1] Luminescent and redox-active polynuclear transition metal complexes
Balzani, V
Juris, A
Venturi, M
Campagna, S
Serroni, S
[J]. CHEMICAL REVIEWS, 1996, 96 (02) : 759 - 833
[2] Vectorial transfer of electronic energy in rod-like ruthenium-osmium dinuclear complexes
Barigelletti, F
Flamigni, L
Collin, JP
Sauvage, JP
[J]. CHEMICAL COMMUNICATIONS, 1997, (04) : 333 - 338
[3] RIGID ROD-LIKE DINUCLEAR RU(II) OS(II) TERPYRIDINE-TYPE COMPLEXES - ELECTROCHEMICAL-BEHAVIOR, ABSORPTION-SPECTRA, LUMINESCENCE PROPERTIES, AND ELECTRONIC-ENERGY TRANSFER THROUGH PHENYLENE BRIDGES
BARIGELLETTI, F
FLAMIGNI, L
BALZANI, V
COLLIN, JP
SAUVAGE, JP
SOUR, A
CONSTABLE, EC
THOMPSON, AMWC
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (17) : 7692 - 7699
[4] STRATEGIES FOR THE ASSEMBLY OF HOMO-NUCLEAR AND HETERO-NUCLEAR METALLOSUPRAMOLECULES CONTAINING 2,2'/6',2''-TERPYRIDINE METAL-BINDING DOMAINS
CONSTABLE, EC
THOMPSON, AMWC
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (10): : 1615 - 1627
[5] DECOLA L, 1992, NATO ADV SCI I C-MAT, V371, P157
[6] Proton-induced switching of electron transfer pathways in dendrimer-type tetranuclear RuOs3 complexes
Haga, MA
Ali, M
Arakawa, R
[J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1996, 35 (01): : 76 - 78
[7] Making photoactive molecular-scale wires
Harriman, A
Ziessel, R
[J]. CHEMICAL COMMUNICATIONS, 1996, (15) : 1707 - 1716
[8] Strategy for constructing photosynthetic models: Porphyrin-containing modules assembled around transition metals
Harriman, A
Sauvage, JP
[J]. CHEMICAL SOCIETY REVIEWS, 1996, 25 (01) : 41 - &
[9] Photoinduced electron and energy transfer in rigidly bridged Ru(II)-Rh(III) binuclear complexes
Indelli, MT
Scandola, F
Collin, JP
Sauvage, JP
Sour, A
[J]. INORGANIC CHEMISTRY, 1996, 35 (02) : 303 - 312
[10] INTER-CHROMOPHORE ELECTRONIC INTERACTIONS IN LIGAND-BRIDGED POLYNUCLEAR COMPLEXES - A COMPARATIVE-STUDY OF VARIOUS BRIDGING LIGANDS
KALYANASUNDARAM, K
NAZEERUDDIN, MK
[J]. INORGANICA CHIMICA ACTA, 1994, 226 (1-2) : 213 - 230

← 1 2 →