Photochromic amorphous molecular materials based on dibenzothienylthiazole structure

被引:39
作者
Kawai, Shigekazu [1 ]
Nakashima, Takuya [1 ]
Kutsunugi, Yuuichirou [1 ]
Nakagawa, Hisako [1 ]
Nakano, Hideyuki [2 ]
Kawai, Tsuyoshi [1 ]
机构
[1] Nara Inst Sci & Technol, Grad Sch Mat Sci, Nara 6300192, Japan
[2] Osaka Univ, Grad Sch Engn, Suita, Osaka 565, Japan
关键词
RELIEF GRATING FORMATION; REFRACTIVE-INDEX CHANGE; DIARYLETHENE SINGLE-CRYSTAL; NONDESTRUCTIVE READOUT; REVERSIBLE PHOTOCYCLIZATION; EUROPIUM(III) COMPLEX; CONDUCTING POLYMER; DITHIENYLETHENE; DYE; FLUORESCENCE;
D O I
10.1039/b823354c
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Terarylene derivatives having benzothienyl moieties, 4,5-bis(2-methylbenzo[b]thiophene-3-yl)-2phenylthiazole, 4,5-di(benzo[b]thiophen-3-yl)-2-phenylthiazole are synthesized and their photochromic properties are studied. These photochromic molecules show fairly high photoreactivities in both solution and bulk amorphous film, and show relatively high glass-transition temperatures. The former molecule shows photochromic reactivity even in the single crystalline phase.
引用
收藏
页码:3606 / 3611
页数:6
相关论文
共 72 条
[1]   Photoswitchable molecular receptors [J].
Alfimov, MV ;
Fedorova, OA ;
Gromov, SP .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2003, 158 (2-3) :183-198
[2]   Two-photon photochromism of an organic material for holographic recording [J].
Belfield, KD ;
Liu, Y ;
Negres, RA ;
Fan, M ;
Pan, G ;
Hagan, DJ ;
Hernandez, FE .
CHEMISTRY OF MATERIALS, 2002, 14 (09) :3663-3667
[3]   Large and stable refractive index change in photochromic hybrid materials [J].
Biteau, J ;
Chaput, F ;
Lahlil, K ;
Boilot, JP ;
Tsivgoulis, GM ;
Lehn, JM ;
Darracq, B ;
Marois, C ;
Levy, Y .
CHEMISTRY OF MATERIALS, 1998, 10 (07) :1945-1950
[4]  
Brown G.H., 1971, Photochromism
[5]   Refractive index change of an amorphous bisbenzothienylethene [J].
Chauvin, J ;
Kawai, T ;
Irie, M .
JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS BRIEF COMMUNICATIONS & REVIEW PAPERS, 2001, 40 (4A) :2518-2522
[6]  
Crano JC, 1999, T APPL CHEM, P1
[7]   One-way optoelectronic switching of photochromic molecules on gold [J].
Dulic, D ;
van der Molen, SJ ;
Kudernac, T ;
Jonkman, HT ;
de Jong, JJD ;
Bowden, TN ;
van Esch, J ;
Feringa, BL ;
van Wees, BJ .
PHYSICAL REVIEW LETTERS, 2003, 91 (20)
[8]   SELF-HOLDING PHOTOCHROMIC POLYMER MACH-ZEHNDER OPTICAL SWITCH [J].
EBISAWA, F ;
HOSHINO, M ;
SUKEGAWA, K .
APPLIED PHYSICS LETTERS, 1994, 65 (23) :2919-2921
[9]   Three-dimensional erasable optical memory using a photochromic diarylethene single crystal as the recording medium [J].
Fukaminato, T ;
Kobatake, S ;
Kawai, T ;
Irie, M .
PROCEEDINGS OF THE JAPAN ACADEMY SERIES B-PHYSICAL AND BIOLOGICAL SCIENCES, 2001, 77 (02) :30-35
[10]   Photochromism of a dithienylethene having diphenylamino side groups in the bulk amorphous phase [J].
Fukudome, M ;
Kamiyama, K ;
Kawai, T ;
Irie, M .
CHEMISTRY LETTERS, 2001, (01) :70-71