Lithium Based Metal-Organic Framework with Exceptional Stability

被引：89

作者：

Banerjee, Debasis ^{[1
]}

Kim, Sun Jin ^{[2
]}

Parise, John B. ^{[1
,3
]}

机构：

[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA

[2] Korea Inst Sci & Technol, Nanomat Res Ctr, Seoul 130650, South Korea

[3] SUNY Stony Brook, Dept Geosci, Stony Brook, NY 11794 USA

来源：

CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 05期

基金：

美国国家科学基金会;

关键词：

HYDROGEN STORAGE; COORDINATION POLYMER; STRUCTURAL-CHARACTERIZATION; CARBON-DIOXIDE; GAS SORPTION; ADSORPTION; CAPACITY; SEPARATION; TRIAZOLE; NETWORK;

D O I：

10.1021/cg8014157

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A three-dimensional lithium based metal-organic framework Li-2(2,6-NDC) (1); UL-MOF-1, UL ultralight; NDC = napthalenedicarboxylate; space group P2(1)/c, a = 10.302(5), b = 5.345(2), c = 8.663(4) angstrom, beta = 98.659(9)degrees, V = 471.6(4) angstrom(3) was synthesized. The framework is stable to 610 degrees C. The synthesis of 1 was achieved using solvothermal methods in N,N-dimethylformamide at 180 degrees C and was characterized by single crystal X-ray diffraction. The structure consists of layers of two-dimensional antifluorite related LiO connected by the NDC linker.

引用

页码：2500 / 2503

页数：4

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