Lithium Based Metal-Organic Framework with Exceptional Stability

被引：89

作者：

Banerjee, Debasis ^{[1
]}

Kim, Sun Jin ^{[2
]}

Parise, John B. ^{[1
,3
]}

机构：

[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA

[2] Korea Inst Sci & Technol, Nanomat Res Ctr, Seoul 130650, South Korea

[3] SUNY Stony Brook, Dept Geosci, Stony Brook, NY 11794 USA

来源：

CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 05期

基金：

美国国家科学基金会;

关键词：

HYDROGEN STORAGE; COORDINATION POLYMER; STRUCTURAL-CHARACTERIZATION; CARBON-DIOXIDE; GAS SORPTION; ADSORPTION; CAPACITY; SEPARATION; TRIAZOLE; NETWORK;

D O I：

10.1021/cg8014157

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A three-dimensional lithium based metal-organic framework Li-2(2,6-NDC) (1); UL-MOF-1, UL ultralight; NDC = napthalenedicarboxylate; space group P2(1)/c, a = 10.302(5), b = 5.345(2), c = 8.663(4) angstrom, beta = 98.659(9)degrees, V = 471.6(4) angstrom(3) was synthesized. The framework is stable to 610 degrees C. The synthesis of 1 was achieved using solvothermal methods in N,N-dimethylformamide at 180 degrees C and was characterized by single crystal X-ray diffraction. The structure consists of layers of two-dimensional antifluorite related LiO connected by the NDC linker.

引用

页码：2500 / 2503

页数：4

共 40 条

[11] Reversible anion exchanges between the layered organic-inorganic hybridized architectures: Syntheses and structures of manganese(II) and copper(II) complexes containing novel tripodal ligands [J].

Fan, J ;

Gan, L ;

Kawaguchi, H ;

Sun, WY ;

Yu, KB ;

Tang, WX .

CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (16) :3965-3973

[12] Structure, luminescence, and adsorption properties of two chiral microporous metal-organic frameworks [J].

Fang, QR ;

Zhu, GS ;

Xue, M ;

Sun, JY ;

Sun, FX ;

Qiu, SL .

INORGANIC CHEMISTRY, 2006, 45 (09) :3582-3587

[13] Adsorption of molecular hydrogen on coordinatively unsaturated Ni(II) sites in a nanoporous hybrid material [J].

Forster, Paul M. ;

Eckert, Juergen ;

Heiken, Brandon D. ;

Parise, John B. ;

Yoon, Ji Woong ;

Jhung, Sung Hwa ;

Chang, Jong-San ;

Cheetham, Anthony K. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2006, 128 (51) :16846-16850

[14] Synthesis, structure and luminescent properties of rare earth coordination polymers constructed from paddle-wheel building blocks [J].

Guo, XD ;

Zhu, GS ;

Fang, QR ;

Xue, M ;

Tian, G ;

Sun, JY ;

Li, XT ;

Qiu, SL .

INORGANIC CHEMISTRY, 2005, 44 (11) :3850-3855

[15] Covalent organic frameworks as exceptional hydrogen storage materials [J].

Han, Sang Soo ;

Furukawa, Hiroyasu ;

Yaghi, Omar M. ;

Goddard, William A., III .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (35) :11580-+

[16] Improving hydrogen storage capacity of MOF bv functionalization of the organic linker with lithium atoms [J].

Klontzas, Emmanouel ;

Mavrandonakis, Andreas ;

Tylianakis, Emmanuel ;

Froudakis, George E. .

NANO LETTERS, 2008, 8 (06) :1572-1576

[17] The 3D channel framework based on indium(III)-btec, and its ion-exchange properties (btec=1,2,4,5-benzenetetracarboxylate) [J].

Lin, ZZ ;

Jiang, FL ;

Yuan, DQ ;

Chen, L ;

Zhou, YF ;

Hong, MC .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (10) :1927-1931

[18] A novel 2-D honeycomb-like lithium coordination polymer containing 42-membered rings [J].

Liu, X ;

Guo, GC ;

Liu, B ;

Chen, WT ;

Huang, JS .

CRYSTAL GROWTH & DESIGN, 2005, 5 (03) :841-843

[19] A novel stair-like lithium coordination polymer constructed from 4,4′-bipyridine [J].

Liu, X ;

Guo, GC ;

Wu, AQ ;

Huang, JS .

INORGANIC CHEMISTRY COMMUNICATIONS, 2004, 7 (12) :1261-1263

[20] Lithium-based 3D coordination polymer with hydrophilic structure for sensing of solvent molecules [J].

Liu, Ying-Ya ;

Zhang, Jian ;

Xu, Fen ;

Sun, Li-Xian ;

Zhang, Tao ;

You, Wan-Sheng ;

Zhao, Yi ;

Zeng, Julan ;

Cao, Zhong ;

Yang, Daowu .

CRYSTAL GROWTH & DESIGN, 2008, 8 (09) :3127-3129

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