Reverse micelle synthesis and characterization of ZnSe nanoparticles

被引:142
作者
Quinlan, FT
Kuther, J
Tremel, W
Knoll, W
Risbud, S
Stroeve, P [1 ]
机构
[1] Univ Calif Davis, Ctr Polymer Interfaces & Macromol Assemblies, Dept Chem Engn & Mat Sci, Davis, CA 95616 USA
[2] Univ Mainz, Inst Anorgan Chem & Analyt Chem, D-55099 Mainz, Germany
[3] Max Planck Inst Polymerforsch, D-55128 Mainz, Germany
关键词
D O I
10.1021/la9909291
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanoparticles of ZnSe were synthesized using the reverse micelle technique. The nanoparticle exhibit quantum confinement, having radii less than that of the Bohr exciton radius. X-ray diffraction analysis shows that the nanoparticles are cubic ZnSe. Light scattering and transmission electron microscopy measurements give the diameters of the nanoparticles to be from 3.3-3.5 nm. The absorption shift in the ultraviolet-visible spectra shows an offset of 0.6 eV, and the peak emission of the nanoparticles is 355 nm, as obtained by photoluminescence.
引用
收藏
页码:4049 / 4051
页数:3
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